- Made a nude artistic calendar in 2004 for the Italian magazine Max.
- Used to work as a bartender in a club.
- Has a degree in Economics.
- Always had a passion for sports, especially skiing, snowboarding, tennis, soccer and swimming.
- Was a tennis champion during his teen years.
- Cousin of Alessia Ventura. She subscribed him to the "Grande Fratello"'s castings. Brother of Francesca Argentero.
- 2007: lives with his companion of three years, Myriam Catania. They met on the set of Carabinieri (2002).
- Proposed twice to his girlfriend Myriam Catania before she accepted to marry him.
- Quit smoking for eight months but started again because his character in "Il Grande Sogno" was a smoker.
- Former son-in-law of Vincenzo Catania and Rossella Izzo. Former brother-in-law of Giulia and Gianmario Catania.
- Dating Cristina Marino (2016).
- Luca and Cristina Marino have two children, daughter Nina Speranza (b. May 20th 2020) and son Roberto Noè (b. February 16th, 2023).
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